SciPost Phys. 15, 163 (2023) ·
published 16 October 2023
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Polymer chains decorated with a fraction of monomers capable of forming reversible bonds form transient polymer networks that are important in soft and biological systems. If chains are flexible and the attractive monomers are all of the same species, the network formation occurs continuously as density increases. By contrast, it has been recently shown [Phys. Rev. Lett. 129, 047801 (2022)] that, if the attractive monomers are of two different and alternating types, the entropic gain of swapping intra-molecular bonds for inter-molecular connections induces a first order phase transition in the fully-bonded (i.e. low-temperature or, equivalently, large monomer-monomer attraction strength) limit and the network forms abruptly on increasing density. Here we use simulations to show that this phenomenon is robust with respect to thermal fluctuations, disorder and change in the polymer architecture, demonstrating its generality and likely relevance for the wide class of materials that can be modelled as associative (transient) polymer networks.
SciPost Phys. 15, 164 (2023) ·
published 16 October 2023
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The characterization of density correlations in the presence of strongly fluctuating interfaces has always been considered a difficult problem in statistical mechanics. Here we study - by using recently developed exact field-theoretical techniques - density correlations for an interface with endpoints on a wall forming a droplet in 2D. Our framework applies to interfaces entropically repelled by a hard wall as well as to wetting transitions. In the former case bubbles adsorbed on the interface are taken into account by the theory which yields a systematic treatment of finite-size corrections to one- and two-point functions and show how these are related to Brownian excursions. Our analytical predictions are confirmed by Monte Carlo simulations without free parameters. We also determine one- and two-point functions at wetting by using integrable boundary field theory. We show that correlations are long ranged for entropic repulsion and at wetting. For both regimes we investigate correlations in momentum space by generalizing the notion of interface structure factor to semi-confined systems. Distinctive signatures of the two regimes manifest in the structure factor through a term that we identify on top of the capillary-wave one.
SciPost Phys. 15, 243 (2023) ·
published 18 December 2023
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We consider the transverse field Ising model in (2+1)D, putting 12 spins at the vertices of the regular icosahedron. The model is tiny by the exact diagonalization standards, and breaks rotation invariance. Yet we show that it allows a meaningful comparison to the 3D Ising CFT on $\mathbb{R}× S^2$, by including effective perturbations of the CFT Hamiltonian with a handful of local operators. This extreme example shows the power of conformal perturbation theory in understanding finite N effects in models on regularized $S^2$. Its ideal arena of application should be the recently proposed models of fuzzy sphere regularization.
SciPost Phys. Lect. Notes 76 (2023) ·
published 30 October 2023
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In statistical mechanics, the generally called Stirling approximation is actually an approximation of Stirling's formula. In this article, it is shown that the term that is dropped is in fact the one that takes fluctuations into account. The use of the Stirling's exact formula forces us to reintroduce them into the already proposed solutions of well-know puzzles such as the extensivity paradox or the Gibbs' paradox of joining two volumes of identical gas. This amendment clearly results in a gain in consistency and rigor of these solutions.
