Contributor info: Dr Vasco Cavina

Francesco Avanzini, Massimo Bilancioni, Vasco Cavina, Sara Dal Cengio, Massimiliano Esposito, Gianmaria Falasco, Danilo Forastiere, Nahuel Freitas, Alberto Garilli, Pedro E. Harunari, Vivien Lecomte, Alexandre Lazarescu, Shesha G. Marehalli Srinivas, Charles Moslonka, Izaak Neri, Emanuele Penocchio, William D. Piñeros, Matteo Polettini, Adarsh Raghu, Paul Raux, Ken Sekimoto, Ariane Soret

SciPost Phys. Lect. Notes 80 (2024) · published 20 March 2024 | Toggle abstract · pdf

Lecture notes after the doctoral school (Post)Modern Thermodynamics held at the University of Luxembourg, December 2022, 5-7, covering and advancing continuous-time Markov chains, network theory, stochastic thermodynamics, large deviations, deterministic and stochastic chemical reaction networks, metastability, martingales, quantum thermodynamics, and foundational issues.

Vasco Cavina, Sadeq S. Kadijani, Massimiliano Esposito, Thomas L. Schmidt

SciPost Phys. 15, 209 (2023) · published 27 November 2023 | Toggle abstract · pdf

The work fluctuation theorem (FT) is a symmetry connecting the moment generating functions (MGFs) of the work extracted in a given process and in its time-reversed counterpart. We show that, equivalently, the FT for work in isolated quantum systems can be expressed as an invariance property of a modified Keldysh contour. Modified contours can be used as starting points of perturbative and path integral approaches to quantum thermodynamics, as recently pointed out in the literature. After reviewing the derivation of the contour-based perturbation theory, we use the symmetry of the modified contour to show that the theory satisfies the FT at every order. Furthermore, we extend textbook diagrammatic techniques to the computation of work MGFs, showing that the contributions of the different Feynman diagrams can be added to obtain a general expression of the work statistics in terms of a sum of independent rescaled Poisson processes. In this context, the FT takes the form of a detailed balance condition linking every Feynman diagram with its time-reversed variant. In the second part, we study path integral approaches to the calculation of the MGF, and discuss how the arbitrariness in the choice of the contour impacts the final form of the path integral action. In particular, we show how using a symmetrized contour makes it possible to easily generalize the Keldysh rotation in the context of work statistics, a procedure paving the way to a semiclassical expansion of the work MGF. Furthermore, we use our results to discuss a generalization of the detailed balance conditions at the level of the quantum trajectories.

Antonio D'Abbruzzo, Vasco Cavina, Vittorio Giovannetti

SciPost Phys. 15, 117 (2023) · published 27 September 2023 | Toggle abstract · pdf

We introduce a new regularization of the Redfield equation based on a replacement of the Kossakowski matrix with its closest positive semidefinite neighbor. Unlike most of the existing approaches, this procedure is capable of retaining the time dependence of the Kossakowski matrix, leading to a completely positive divisible quantum process. Using the dynamics of an exactly-solvable three-level open system as a reference, we show that our approach performs better during the transient evolution, if compared to other approaches like the partial secular master equation or the universal Lindblad equation. To make the comparison between different regularization schemes independent from the initial state, we introduce a new quantitative approach based on the Choi-Jamiołkowski isomorphism.